高分子合成技术-2020
甘文君
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1 Chapter 1
1.1 What are Polymers?
1.2 History of Polymer Science
1.3 Definition of Polymers
1.4 Classifications of Polymers
1.5 Naming of Polymers
1.6 Molecular Weight of Polymers
1.7 Physical State
1.8 Thermal Transitions
1.9 Mechnical Properties and Applications
2 Step Polymerization
2.1 Polycondensation
2.2 Linear Polycondensation
2.2.1 Characteristic of linear polycondensation
2.2.2 Molecular Weight Control of Linear Polycondensation
2.2.3 Cyclization Tendency versus Ring Size
2.2.4 Process Condition
2.2.5 Important Linear Polycondensation Polymers
2.3 Crosslinking Polycondensation
2.3.1 Branching
2.3.2 Crosslinking
2.3.3 Gelation and Gel Point
2.3.4 Carothers Equation
2.3.5 Statistical Approach
2.3.6 Important Crosslinking Polymers
2.4 Step-growth addition Polymerization
2.4.1 Polyurethane
2.4.2 Reactants and Catalyst
2.4.3 Reaction Mechsnism and Reactivity
2.4.4 Difficult and Opportunity
3 Chain Polymerization
3.1 Thermodynamics
3.2 Radical Polymerization
3.2.1 Elementary Reactions
3.2.2 Characteristics
3.2.3 Initiator
3.2.4 Monomoer Structure and Polymerization Mechanism
3.2.5 Rate of Radical Chain Polymerization
3.2.6 Molecular Weight
3.3 Chain Copolymerization
3.3.1 Copolymer composition
3.3.2 Types of Copolymerizaiton Behavior
3.3.3 Variation of Composition with Conversion
3.3.4 Radical Copolymerization and Reactivity
3.3.5 Ionic Copolymerization
3.4 Ionic Polymerization
3.4.1 Anionic Polymerization
3.4.2 Cationic Polymerization
3.5 Physical Methods
Molecular Weight of Polymers
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